Novel, High-yielding Synthesis of meso-Substituted Porphyrins via the Direct Arylation of Porphine.
Wheelhouse, Richard T. Shi, D-F.
Wheelhouse, Richard T.
Shi, D-F.
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2002
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Abstract
A new method for the synthesis of meso-substituted porphyrins is described: reaction of 5,10,15,20-tetrabromoporphine magnesium complex with aryl or heteroaryl boronic acids in the presence of Pd(PPh3)4 gave meso-substituted porphyrins in yields up to 70%.
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Shi, D-F. and Wheelhouse, R.T. (2002). Novel, High-yielding Synthesis of meso-Substituted Porphyrins via the Direct Arylation of Porphine. Tetrahedron Letters. Vol. 43, No. 51, pp. 9341-9342.
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