Publication

Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst

Schumacher, C.
; 
Crawford, Deborah E.
; 
Raguž, B.
; 
Glaum, R.
; 
James, S.L.
; 
Bolm, C.
; 
Hernández, J.G.
Publication Date
2018-07
End of Embargo
Supervisor
Keywords
Mechanochemistry, Wilkinson's catalyst, Dehydrocoupling, Ball milling
Rights
Peer-Reviewed
Yes
Open Access status
closedAccess
Accepted for publication
2018-07-05
Institution
Department
Awarded
Embargo end date
Collections
Life Sciences Publications
Show all metadata
Additional title
Abstract
Mechanochemistry enabled the selective synthesis of the recherche´ orange polymorph of Wilkinson’s catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.
URI
http://hdl.handle.net/10454/17697
Version
No full-text in the repository
Citation
Schumacher C, Crawford DE, Raguž B et al (2018) Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. Chemical Communications. 54(60): 8355-8358.
Link to publisher’s version
Link to published version
Link to Version of Record
https://doi.org/10.1039/C8CC04487B
Type
Article
Qualification name
Notes