Schumacher, C.Crawford, Deborah E.Raguž, B.Glaum, R.James, S.L.Bolm, C.Hernández, J.G.2020-03-032020-03-092020-03-032020-03-092018-07Schumacher C, Crawford DE, Raguž B et al (2018) Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. Chemical Communications. 54(60): 8355-8358.RMSID:212563914http://hdl.handle.net/10454/17697NoMechanochemistry enabled the selective synthesis of the recherche´ orange polymorph of Wilkinson’s catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.enMechanochemistryWilkinson's catalystDehydrocouplingBall millingArticlehttps://doi.org/10.1039/C8CC04487B2020-03-03