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    Easy and Fast Phase Transfer of CTAB Stabilised Gold Nanoparticles from Water to Organic Phase

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    Publication date
    2015-02-28
    Author
    Kittler, S.
    Hickey, Stephen G.
    Wolff, T.
    Eychmüller, A.
    Keyword
    Phase transfer
    ; Gold
    ; Nanorods
    ; CTAB
    ; Metal nanoparticles
    ; Shape separation
    ; Ligand-exchange
    ; Nanorods
    ; Size
    ; Surface
    ; Solvents
    ; Liquid
    ; Centrifugation
    ; Nanocrystals
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    Peer-Reviewed
    Yes
    
    Metadata
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    Abstract
    Spheric and anisotropic gold nanoparticles (GNPs) such as rods, stars or nanoprism prepared using hexadecyltrimethyl ammonium bromide (CTAB) as the stabilising agent have received a great deal of interest in the last years. The literature procedures exploited lead to GNPs in aqueous solution. We herein describe a fast, efficient, and cheap method to transfer particles of different shapes from water into toluene solution via ligand exchange (CTAB to dodecanethiol), which was mediated by acetone as a cosolvent. Absorption spectra and TEM-pictures before and after the transfer revealed that the particles survived the transfer intact and without change in shape.
    URI
    http://hdl.handle.net/10454/9367
    Version
    No full-text available in the repository
    Citation
    Kittler S, Hickey SG, Wolff T et al (2015) Easy and Fast Phase Transfer of CTAB Stabilised Gold Nanoparticles from Water to Organic Phase. Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics. 229(1-2): 235-245.
    Link to publisher’s version
    http://dx.doi.org/10.1515/zpch-2014-0647
    Type
    Article
    Collections
    Life Sciences Publications

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