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dc.contributor.authorKalidindi, S.B.*
dc.contributor.authorNayak, Sanjit*
dc.contributor.authorBriggs, M.E.*
dc.contributor.authorJansat, S.*
dc.contributor.authorKatsoulidis, A.P.*
dc.contributor.authorMiller, G.J.*
dc.contributor.authorWarren, J.E.*
dc.contributor.authorAntypov, D.*
dc.contributor.authorCora, F.*
dc.contributor.authorSlater, B.*
dc.contributor.authorPrestly, M.R.*
dc.contributor.authorMarti-Gastaldo, C.*
dc.contributor.authorRosseinsky, M.J.*
dc.date.accessioned2016-07-27T16:12:17Z
dc.date.available2016-07-27T16:12:17Z
dc.date.issued2015-01-02
dc.identifier.citationKalidindi SB, Nayak S, Briggs ME et al. (2015) Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering. Angewandte Chemie International Edition. 54(1): 221-226.en_US
dc.identifier.urihttp://hdl.handle.net/10454/8713
dc.descriptionYesen_US
dc.description.abstractThe synthesis of metal–organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1=4,4′,4′′,4′′′-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2=4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayltetrakis(ethyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]⋅(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m2 g−1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.en_US
dc.description.sponsorshipFinancial support from EPSRC under EP/H000925, access to the HPC service ARCHER via EP/L000202. S.N. thanks the EU for a Marie Curie fellowship (PIEF-GA-2010-274952). C.M.-G. thanks the Spanish MINECO for a Ramón y Cajal Fellowship (RYC-2012-10894).en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttp://dx.doi.org/10.1002/anie.201406501en_US
dc.rights© 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.en_US
dc.subjectMesoporous materials; Metal–organic frameworks; Water stability; Zirconiumen_US
dc.titleChemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineeringen_US
dc.status.refereedYesen_US
dc.date.Accepted2014
dc.date.application2014-12-17
dc.typeArticleen_US
dc.type.versionpublished version paperen_US
refterms.dateFOA2018-07-25T12:24:45Z


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