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    Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

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    Publication date
    2015-01-02
    Author
    Kalidindi, S.B.
    Nayak, Sanjit
    Briggs, M.E.
    Jansat, S.
    Katsoulidis, A.P.
    Miller, G.J.
    Warren, J.E.
    Antypov, D.
    Cora, F.
    Slater, B.
    Prestly, M.R.
    Marti-Gastaldo, C.
    Rosseinsky, M.J.
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    Keyword
    Mesoporous materials; Metal–organic frameworks; Water stability; Zirconium
    Rights
    © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
    Peer-Reviewed
    Yes
    
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    Abstract
    The synthesis of metal–organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1=4,4′,4′′,4′′′-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2=4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayltetrakis(ethyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]⋅(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m2 g−1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.
    URI
    http://hdl.handle.net/10454/8713
    Version
    published version paper
    Citation
    Kalidindi SB, Nayak S, Briggs ME et al. (2015) Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering. Angewandte Chemie International Edition. 54(1): 221-226.
    Link to publisher’s version
    http://dx.doi.org/10.1002/anie.201406501
    Type
    Article
    Collections
    Life Sciences Publications

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