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    Reduction of Propargylic Sulfones to (Z)-Allylic Sulfones using Zinc and Ammonium Chloride.

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    Publication date
    2007
    Author
    Sheldrake, Helen M.
    Wallace, T.W.
    Keyword
    Propargylic sulfone
    Allylsulfone
    cis-Hydrogenation
    Reduction
    Zinc
    Peer-Reviewed
    Yes
    
    Metadata
    Show full item record
    Abstract
    Propargylic sulfones can be cis-hydrogenated using commercial zinc powder and ammonium chloride in THF¿water at room temperature, the major products being the corresponding (Z)-allylic sulfones. Other reducible groups (alkene, benzyloxy) are not affected. Allenylsulfones are implicated in one of the possible reaction pathways.
    URI
    http://hdl.handle.net/10454/3451
    Version
    No full-text available in the repository
    Citation
    Sheldrake, H.M. and Wallace, T.W. (2007). Reduction of Propargylic Sulfones to (Z)-Allylic Sulfones using Zinc and Ammonium Chloride. Tetrahedron Letters. Vol. 48, No. 25, pp. 4407-4411.
    Link to publisher’s version
    http://dx.doi.org/10.1016/j.tetlet.2007.04.099
    Type
    Article
    Collections
    Life Sciences Publications

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