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dc.contributor.authorLong, R.
dc.contributor.authorHuang, S.
dc.contributor.authorWu, Han-Kui
dc.contributor.authorIqbal, Naila
dc.contributor.authorWu, Na
dc.date.accessioned2023-07-13T14:12:00Z
dc.date.accessioned2023-07-20T09:08:46Z
dc.date.available2023-07-13T14:12:00Z
dc.date.available2023-07-20T09:08:46Z
dc.date.issued2023
dc.identifier.citationLong R, Huang S, Wu H-K et al (2023) Metal-Free Oxyacetoxylation of Arylynamines and Ynamides to Construct α-Acetoxyl Amides. European Journal of Organic Chemistry. 26(32): e202300393.en_US
dc.identifier.urihttp://hdl.handle.net/10454/19527
dc.descriptionYesen_US
dc.description.abstractYnamides/arylynamines are challenging substrates for oxyacetoxylation, especially due to various reactive sites of N-heteroaryl ring. Herein we report a metal-free PhI(OAc)2-mediated oxyacetoxylation of arylynamines / ynamides to provide α-acetoxyl amides in good to excellent yields. The transformation completes in a short time to afford solely the product without functionalising N-heteroaryl moiety, in a highly regio- and chemo-selective manner through β-iodo keteneiminium intermediate.en_US
dc.language.isoenen_US
dc.rights© 2023 Wiley. This is the peer-reviewed version of the following article: Long R, Huang S, Wu H-K et al (2023) Metal-Free Oxyacetoxylation of Arylynamines and Ynamides to Construct α-Acetoxyl Amides. European Journal of Organic Chemistry. vol 26(32): e202300393 which has been published in final form at https://doi.org/10.1002/ejoc.202300393. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en_US
dc.subjectYnamidesen_US
dc.subjectArylynaminesen_US
dc.subjectOxyacetoxylationen_US
dc.titleMetal-Free Oxyacetoxylation of Arylynamines and Ynamides to Construct α-Acetoxyl Amidesen_US
dc.status.refereedYesen_US
dc.date.Accepted2023-06-27
dc.date.application2023-06-28
dc.typeArticleen_US
dc.date.EndofEmbargo2023-06-28
dc.type.versionAccepted manuscripten_US
dc.description.publicnotesThe full-text of this article will be released for public view at the end of the publisher embargo on 28 Jun 2024.en_US
dc.identifier.doihttps://doi.org/10.1002/ejoc.202300393
dc.rights.licenseUnspecifieden_US
dc.date.updated2023-07-13T14:12:03Z
refterms.dateFOA2023-07-20T09:09:20Z
dc.openaccess.statusembargoedAccessen_US


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