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dc.contributor.authorHuang, S.
dc.contributor.authorMa, J.
dc.contributor.authorYi, Y.
dc.contributor.authorLi, M.
dc.contributor.authorCai, P.
dc.contributor.authorWu, Na (Anna)
dc.date.accessioned2022-07-24T18:23:43Z
dc.date.accessioned2022-07-28T15:23:30Z
dc.date.available2022-07-24T18:23:43Z
dc.date.available2022-07-28T15:23:30Z
dc.date.issued2022-04
dc.identifier.citationHuang S, Ma J, Yi Y et al (2022) Synthesis of orthogonal push-pull chromophores via click reaction of arylynamines. Organic and Biomolecular Chemistry. 20: 4081-4085.en_US
dc.identifier.urihttp://hdl.handle.net/10454/19083
dc.descriptionYesen_US
dc.description.abstractHerein, we report a catalyst-free ‘click’ reaction: metal-free [2 + 2] cycloaddition–retro-electrocyclisation (CA–RE) of arylynamines with the sluggish acceptor tetracyanoquinodimethane (TCNQ) to provide orthogonal electron-push–pull light-harvesting small molecules: N-heterocyclic dicyanoquinodimethane-substituted methylene malononitriles. Ynamines are reactive alkynes and tend to induce over-reactions with the CA–RE adducts. The reactivity of arylynamines was balanced properly by ensuring the electrondensity of the nitrogen atom was delocalised more over the aromatic rings than the triple bond.en_US
dc.description.sponsorshipThis work was supported by Guangxi Natural Science Foundation (2020JJA120032).en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1039/D2OB00677Den_US
dc.rights© The Royal Society of Chemistry 2022. Reproduced in accordance with the publisher's self-archiving policy.en_US
dc.subjectClick reactionen_US
dc.subjectOrthogonal push–pull chromophoresen_US
dc.subjectArylynaminesen_US
dc.subjectResearch Development Fund Publication Prize Award
dc.titleSynthesis of orthogonal push-pull chromophores via click reaction of arylynaminesen_US
dc.status.refereedYesen_US
dc.date.Accepted2022-04-28
dc.date.application2022-04-28
dc.typeArticleen_US
dc.date.EndofEmbargo2023-04-28
dc.type.versionAccepted manuscripten_US
dc.description.publicnotesThe full-text of this article will be released for public view at the end of the publisher embargo on 28 Apr 2023.en_US
dc.description.publicnotesResearch Development Fund Publication Prize Award winner, April 2022.
dc.rights.licenseUnspecifieden_US
dc.date.updated2022-07-24T18:23:46Z
refterms.dateFOA2022-07-28T15:23:56Z
dc.openaccess.statusembargoedAccessen_US


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