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dc.contributor.authorSiyu, Y.
dc.contributor.authorWu, Na (Anna)
dc.date.accessioned2021-03-30T19:20:41Z
dc.date.accessioned2021-04-15T11:19:48Z
dc.date.available2021-03-30T19:20:41Z
dc.date.available2021-04-15T11:19:48Z
dc.date.issued2020
dc.identifier.citationSiyu Y and Wu N (2020) The Chemistry of Ynamide and its Application in Organic Synthesis. In: Rahman AU (Ed) Advances in Organic Synthesis. Volume 13. Singapore: Bentham Science Publishers.en_US
dc.identifier.urihttp://hdl.handle.net/10454/18435
dc.descriptionYesen_US
dc.description.abstractYnamide, is an understudied but attractive class of alkynes, activated by the donating ability of the nitrogen adjacent to alkynes. With the nucleophilicity on β-carbon and the electrophilicity on α-carbon of ynamides, this review summarizes the syntheses of ynamides and miscellaneous reactions - oxidation, rearrangement, cyclization, and cycloaddition to construct complicated heterocyclic rings. The synthetic methodologies were further applied into natural products synthesis, e.g. marinoquinolines A and C, aplidiopsamine A, rigidin A, and 7-azaserotonin derivative.en_US
dc.description.sponsorshipWe thank National Science Foundation of China (NSFC) (21462004), State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (CMEMR2014-A04), 2015 GXNSFBA (139032), GXNU, and Newton International Fellowship granted by Royal Society.en_US
dc.language.isoenen_US
dc.publisherBentham Science Publishers
dc.subjectYnamideen_US
dc.subjectYndiamideen_US
dc.subjectThioenamideen_US
dc.subjectHaloenamideen_US
dc.subjectKeteniminiumen_US
dc.subjectWitulski rearrangmenten_US
dc.subjectUllmann couplingen_US
dc.subjectDipolar cycloadditionen_US
dc.subjectα-ketoimideen_US
dc.subjectPolycyclic alkaloidsen_US
dc.titleThe Chemistry of Ynamide and its Application in Organic Synthesisen_US
dc.status.refereedYesen_US
dc.typeBook chapteren_US
dc.type.versionAccepted manuscripten_US
dc.identifier.doihttps://doi.org/10.2174/9789811405082120130004
dc.date.updated2021-03-30T18:20:52Z
refterms.dateFOA2021-04-15T11:20:27Z
dc.openaccess.statusGreenen_US


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