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TfOH-catalyzed reaction of bispropargyl alcohols with 1,3-dicarbonyl compounds

dc.contributor.authorTeng, Q.
dc.contributor.authorMo, S.
dc.contributor.authorPan, J.
dc.contributor.authorWu, Na (Anna)
dc.contributor.authorWang, H.
dc.contributor.authorPan, Y.
dc.date.accessioned2020-06-03T10:03:30Z
dc.date.accessioned2020-06-25T13:40:29Z
dc.date.available2020-06-03T10:03:30Z
dc.date.available2020-06-25T13:40:29Z
dc.date.issued2016
dc.identifier.citationTeng Q, Mo S, Pan J et al (2016) TfOH-catalyzed reaction of bispropargyl alcohols with 1,3-dicarbonyl compounds. Synthesis. 48(3): 455-461.en_US
dc.identifier.urihttp://hdl.handle.net/10454/17870
dc.descriptionNoen_US
dc.description.abstractA transition-metal-free efficient method for the preparation of 1,2,3-trisubstituted benzenes from bispropargyl alcohols and 1,3-dicarbonyl compounds has been developed. The reaction of bispropargyl alcohol with 1,3-dicarbonyl compound proceeds through [3,3]-rearrangement, 6π-electrocyclization, and unexpected Csp3−Csp2 regioselective σ-bond cleavage processes.en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1055/s-0035-1560372en_US
dc.subjectBispropargyl alcoholsen_US
dc.subject1,3-dicarbonyl compoundsen_US
dc.subject[3,3]-rearrangementen_US
dc.subjectC−C α′-moiety cleavageen_US
dc.subject6π-electrocyclization processen_US
dc.subject1,2,3-trisubstituted benzenesen_US
dc.titleTfOH-catalyzed reaction of bispropargyl alcohols with 1,3-dicarbonyl compoundsen_US
dc.status.refereedYesen_US
dc.date.Accepted2015-10-15
dc.date.application2015-11-17
dc.typeArticleen_US
dc.type.versionNo full-text in the repositoryen_US
dc.date.updated2020-06-03T09:03:32Z


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