TfOH-catalyzed reaction of bispropargyl alcohols with 1,3-dicarbonyl compounds
Publication date
2016Keyword
Bispropargyl alcohols1
3-dicarbonyl compounds
[3
3]-rearrangement
C−C α′-moiety cleavage
6π-electrocyclization process
1
2
3-trisubstituted benzenes
Peer-Reviewed
YesOpen Access status
closedAccessAccepted for publication
15/10/2015
Metadata
Show full item recordAbstract
A transition-metal-free efficient method for the preparation of 1,2,3-trisubstituted benzenes from bispropargyl alcohols and 1,3-dicarbonyl compounds has been developed. The reaction of bispropargyl alcohol with 1,3-dicarbonyl compound proceeds through [3,3]-rearrangement, 6π-electrocyclization, and unexpected Csp3−Csp2 regioselective σ-bond cleavage processes.Version
No full-text in the repositoryCitation
Teng Q, Mo S, Pan J et al (2016) TfOH-catalyzed reaction of bispropargyl alcohols with 1,3-dicarbonyl compounds. Synthesis. 48(3): 455-461.Link to Version of Record
https://doi.org/10.1055/s-0035-1560372Type
Articleae974a485f413a2113503eed53cd6c53
https://doi.org/10.1055/s-0035-1560372