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dc.contributor.authorYan, Z.
dc.contributor.authorWu, Na (Anna)
dc.contributor.authorLiang, D.
dc.contributor.authorWang, H.
dc.contributor.authorPan, Y.
dc.date.accessioned2020-06-22T13:59:31Z
dc.date.available2020-06-22T13:59:31Z
dc.date.issued2014-08-01
dc.identifier.citationYan Z, Wu N, Liang D et al (2014) One-Pot Stepwise Approach to β-Enaminoketoesters through “Masked” 1,3-Aza-Dipoles. Organic Letters. 16(15): 4048-4051.en_US
dc.identifier.urihttp://hdl.handle.net/10454/17851
dc.descriptionYesen_US
dc.description.abstractt-BuOK-mediated rearrangement of 1,3-ketoesters with 2-(azidomethyl) aromatics in a two-step, one-pot telescoped sequence affords β-enaminoketoesters in moderate to good yields. A novel pathway is proposed in which the umpolung of the azide is achieved from electrophilicity to nucleophilicity via deprotonation and undergoes nucleophilic attack onto the 1,3-ketoester.en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1021/ol501930fen_US
dc.rights© 2014 ACS. This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer-review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/ol501930f.
dc.subjectAzidesen_US
dc.subjectCyclisationen_US
dc.subjectEstersen_US
dc.subjectKetonesen_US
dc.subjectMolecular structureen_US
dc.subjectStereoisomerismen_US
dc.titleOne-Pot Stepwise Approach to β-Enaminoketoesters through “Masked” 1,3-Aza-Dipolesen_US
dc.status.refereedYesen_US
dc.date.application2014-07-23
dc.typeLetteren_US
dc.type.versionAccepted manuscripten_US
refterms.dateFOA2020-06-23T06:03:12Z


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