A concise and straightforward approach to total synthesis of (+)-Strictifolione and formal synthesis of Cryptofolione via a unified strategy
dc.contributor.author | Li, X. | |
dc.contributor.author | Wang, G. | |
dc.contributor.author | Zhang, Z. | |
dc.contributor.author | Wu, Na | |
dc.contributor.author | Yang, Q. | |
dc.contributor.author | Huang, S. | |
dc.contributor.author | Wang, X. | |
dc.date.accessioned | 2020-05-26T11:21:18Z | |
dc.date.accessioned | 2020-06-22T13:37:25Z | |
dc.date.available | 2020-05-26T11:21:18Z | |
dc.date.available | 2020-06-22T13:37:25Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Li X, Wang G, Zhang Z et al (2019) A concise and straightforward approach to total synthesis of (+)-Strictifolione and formal synthesis of Cryptofolione via a unified strategy. Synthetic Communications. 49(8): 1031-1039. | |
dc.identifier.uri | http://hdl.handle.net/10454/17850 | |
dc.description | Yes | |
dc.description.abstract | We describe a concise and straightforward approach to the total syntheses of (+)-Strictifolione and Cryptofolione in the longest linear sequences of four steps and six steps from 3-phenyl propanal and trans-cinnamaldehyde, respectively. The route utilized a titanium tetraisopropoxide/(R)-[1,1'-binaphthalene]-2,2'-diol catalyzed Mukaiyama aldol reaction, indium(0)-promoted Barbier reaction, and olefin cross-metathesis as the key reactions. | |
dc.description.sponsorship | National Science Foundation of China [21062088, 21562020, and 21462004], the Science and Technology Plan Project of Jiangxi Province [No. 20151BBG70028, 20142BBE50006] and State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources [CMEMR2014-A04] for the funding support. | |
dc.language.iso | en | |
dc.rights | © 2019 Taylor & Francis. This is an Author's Original Manuscript of an article published by Taylor & Francis in Synthetic Communications on 16 Mar 2019 available online at https://doi.org/10.1080/00397911.2019.1580373 | |
dc.subject | Strictifolione | |
dc.subject | Cryptofolione | |
dc.subject | Total synthesis | |
dc.subject | Barbier reaction | |
dc.subject | Olefin cross-metathesis | |
dc.title | A concise and straightforward approach to total synthesis of (+)-Strictifolione and formal synthesis of Cryptofolione via a unified strategy | |
dc.status.refereed | Yes | |
dc.date.application | 16/03/2019 | |
dc.type | Article | |
dc.type.version | Accepted manuscript | |
dc.identifier.doi | https://doi.org/10.1080/00397911.2019.1580373 | |
dc.rights.license | Unspecified | |
dc.date.updated | 2020-05-26T10:21:18Z | |
refterms.dateFOA | 2020-06-23T08:34:07Z | |
dc.openaccess.status | openAccess | |
dc.date.accepted | 04/02/2019 |