Application of dehydroabietic acid in palladium-catalysed enyne cycloisomerisation
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2017-07Keyword
Asymmetric counteranion-directed catalysisCycloisomerisation
Dehydroabietic acid
Diels-Alder reaction
Enynols
Lactonisation
Palladium
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© 2017 Wiley This is the peer reviewed version of the following article: Wu N, Li R, Cui F et al (2017) Application of dehydroabietic acid in palladium-catalysed enyne cycloisomerisation. Advanced Synthesis & Catalysis. 359(14): 2442-2447, which has been published in final form at https://doi.org/10.1002/adsc.201700061. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.Peer-Reviewed
YesOpen Access status
openAccessAccepted for publication
2017
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Show full item recordAbstract
Dehydroabietic acid (DAA) promotes palladium(0)‐catalysed cyclisations of arene‐tethered 1,7‐enynols and 1,m‐enynoates (m=6,7) to give fused carbocyclic dienes. 6,6,6,5‐Tetracyclic lactones are accessible by one‐pot cycloisomerisation/Diels–Alder reaction/lactonisation from 1,7‐enynols. Furthermore, asymmetric counteranion‐directed catalysis has been developed, which afforded an indene derivative with an all‐carbon quaternary stereogenic center.Version
Accepted manuscriptCitation
Wu N, Li R, Cui F et al (2017) Application of dehydroabietic acid in palladium-catalysed enyne cycloisomerisation. Advanced Synthesis & Catalysis. 359(14): 2442-2447.Link to Version of Record
https://doi.org/10.1002/adsc.201700061Type
Articleae974a485f413a2113503eed53cd6c53
https://doi.org/10.1002/adsc.201700061