Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst
| dc.contributor.author | Schumacher, C. | |
| dc.contributor.author | Crawford, Deborah E. | |
| dc.contributor.author | Raguž, B. | |
| dc.contributor.author | Glaum, R. | |
| dc.contributor.author | James, S.L. | |
| dc.contributor.author | Bolm, C. | |
| dc.contributor.author | Hernández, J.G. | |
| dc.date.accessioned | 2020-03-03T15:21:38Z | |
| dc.date.accessioned | 2020-03-09T15:29:16Z | |
| dc.date.available | 2020-03-03T15:21:38Z | |
| dc.date.available | 2020-03-09T15:29:16Z | |
| dc.date.issued | 2018-07 | |
| dc.identifier.citation | Schumacher C, Crawford DE, Raguž B et al (2018) Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. Chemical Communications. 54(60): 8355-8358. | en_US |
| dc.identifier.uri | http://hdl.handle.net/10454/17697 | |
| dc.description | No | en_US |
| dc.description.abstract | Mechanochemistry enabled the selective synthesis of the recherche´ orange polymorph of Wilkinson’s catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling. | en_US |
| dc.description.sponsorship | We thank the RWTH Aachen University for support from the Distinguished Professorship Program funded by the Excellence Initiative of the German federal and state governments, and the EPSRC for funding (EP/L019655/1). | en_US |
| dc.language.iso | en | en_US |
| dc.relation.isreferencedby | https://doi.org/10.1039/C8CC04487B | en_US |
| dc.subject | Mechanochemistry | en_US |
| dc.subject | Wilkinson's catalyst | en_US |
| dc.subject | Dehydrocoupling | en_US |
| dc.subject | Ball milling | en_US |
| dc.title | Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst | en_US |
| dc.status.refereed | Yes | en_US |
| dc.date.Accepted | 2018-07-05 | |
| dc.date.application | 2018-07-05 | |
| dc.type | Article | en_US |
| dc.type.version | No full-text in the repository | en_US |
| dc.date.updated | 2020-03-03T15:21:39Z |