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dc.contributor.authorSchumacher, C.
dc.contributor.authorCrawford, Deborah E.
dc.contributor.authorRaguž, B.
dc.contributor.authorGlaum, R.
dc.contributor.authorJames, S.L.
dc.contributor.authorBolm, C.
dc.contributor.authorHernández, J.G.
dc.date.accessioned2020-03-03T15:21:38Z
dc.date.accessioned2020-03-09T15:29:16Z
dc.date.available2020-03-03T15:21:38Z
dc.date.available2020-03-09T15:29:16Z
dc.date.issued2018-07
dc.identifier.citationSchumacher C, Crawford DE, Raguž B et al (2018) Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. Chemical Communications. 54(60): 8355-8358.
dc.identifier.urihttp://hdl.handle.net/10454/17697
dc.descriptionNo
dc.description.abstractMechanochemistry enabled the selective synthesis of the recherche´ orange polymorph of Wilkinson’s catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.
dc.description.sponsorshipWe thank the RWTH Aachen University for support from the Distinguished Professorship Program funded by the Excellence Initiative of the German federal and state governments, and the EPSRC for funding (EP/L019655/1).
dc.language.isoen
dc.subjectMechanochemistry
dc.subjectWilkinson's catalyst
dc.subjectDehydrocoupling
dc.subjectBall milling
dc.titleMechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst
dc.status.refereedYes
dc.date.Accepted2018-07-05
dc.date.application2018-07-05
dc.typeArticle
dc.type.versionNo full-text in the repository
dc.identifier.doihttps://doi.org/10.1039/C8CC04487B
dc.date.updated2020-03-03T15:21:39Z
dc.openaccess.statusclosedAccess


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