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    Fluorescent and colorimetric molecular recognition probe for hydrogen bond acceptors

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    Publication date
    2017-11
    Author
    Pike, Sarah J.
    Hunter, C.A.
    Keyword
    Hydrogen bond acceptors
    UV/vis absorption
    Fluorescence emission titrations
    Colorimetric and fluorescent molecular recognition probe
    Rights
    © The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/).
    Peer-Reviewed
    Yes
    
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    Abstract
    The association constants for formation of 1 : 1 complexes between a H-bond donor, 1-naphthol, and a diverse range of charged and neutral H-bond acceptors have been measured using UV/vis absorption and fluorescence emission titrations. The performance of 1-naphthol as a dual colorimetric and fluorescent molecular recognition probe for determining the H-bond acceptor (HBA) parameters of charged and neutral solutes has been investigated in three solvents. The data were employed to establish self-consistent H-bond acceptor parameters (β) for benzoate, azide, chloride, thiocyanate anions, a series of phosphine oxides, phosphate ester, sulfoxide and a tertiary amide. The results demonstrate both the transferability of H-bond parameters between different solvents and the utility of the naphthol-based dual molecular recognition probe to exploit orthogonal spectroscopic techniques to determine the HBA properties of neutral and charged solutes. The benzoate anion is the strongest HBA studied with a β parameter of 15.4, and the neutral tertiary amide is the weakest H-bond acceptor investigated with a β parameter of 8.5. The H-bond acceptor strength of the azide anion is higher than that of chloride (12.8 and 12.2 respectively), and the thiocyanate anion has a β value of 10.8 and thus is a significantly weaker H-bond acceptor than both the azide and chloride anions.
    URI
    http://hdl.handle.net/10454/17685
    Version
    Published version
    Citation
    Pike SJ and Hunter CA (2017) Fluorescent and colorimetric molecular recognition probe for hydrogen bond acceptors. Organic & Biomolecular Chemistry. 15(45): 9603-9610.
    Link to publisher’s version
    https://doi.org/10.1039/C7OB02092A
    Type
    Article
    Collections
    Life Sciences Publications

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