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dc.contributor.authorZimbitas, G.
dc.contributor.authorJawor-Baczynska, A.
dc.contributor.authorVesga, M.J.
dc.contributor.authorJavid, Nadeem
dc.contributor.authorMoore, B.D.
dc.contributor.authorParkinson, J.
dc.contributor.authorSefcik, J.
dc.date.accessioned2019-08-08T11:08:47Z
dc.date.accessioned2019-08-14T10:34:22Z
dc.date.available2019-08-08T11:08:47Z
dc.date.available2019-08-14T10:34:22Z
dc.date.issued2019-10
dc.identifier.citationZimbitas G, Jawor-Baczynska A, Vesga MJ et al (2019) Investigation of molecular and mesoscale clusters in undersaturated glycine aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 579: 123633.en_US
dc.identifier.urihttp://hdl.handle.net/10454/17204
dc.descriptionYesen_US
dc.description.abstractIn this work DLS, NTA, SAXS and NMR were used to investigate populations, size distributions and structure of clusters in undersaturated aqueous solutions of glycine. Molecular and colloidal scale (mesoscale) clusters with radii around 0.3-0.5 nm and 100–150 nm, respectively, were observed using complementary experimental techniques. Molecular clusters are consistent with hydrated glycine dimers present in equilibrium with glycine monomers in aqueous solutions. Mesoscale clusters previously observed in supersaturated glycine solutions appear to be indefinitely stable, in mutual equilibrium within mesostructured undersaturated solutions across all glycine concentrations investigated here, down to as low as 1 mg/g of water.en_US
dc.description.sponsorshipSupported by EPSRC funding via the SynBIM project (Grant Reference EP/P0068X/1) and by the Synchrotron SOLEIL.en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1016/j.colsurfa.2019.123633en_US
dc.rights© 2019 Published by Elsevier B.V. Reproduced in accordance with the publisher's self-archiving policy. This manuscript version is made available under the CC-BY-NC-ND 4.0 license.en_US
dc.subjectClusteringen_US
dc.subjectMesostructured liquid phaseen_US
dc.subjectGlycineen_US
dc.subjectScatteringen_US
dc.titleInvestigation of molecular and mesoscale clusters in undersaturated glycine aqueous solutionsen_US
dc.status.refereedYesen_US
dc.date.Accepted2019-07-01
dc.date.application2019-07-02
dc.typeArticleen_US
dc.type.versionAccepted manuscripten_US
dc.date.updated2019-08-08T10:08:50Z
refterms.dateFOA2019-08-14T10:35:39Z


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