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dc.contributor.authorPitto-Barry, Anaïs*
dc.contributor.authorBarry, Nicolas P.E.*
dc.date.accessioned2019-05-29T07:35:17Z
dc.date.available2019-05-29T07:35:17Z
dc.date.issued2018-11-16
dc.identifier.citationPitto-Barry A and Barry NPE (2018) Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex. ACS Omega. 3(11): 15623-15627.en_US
dc.identifier.urihttp://hdl.handle.net/10454/17073
dc.descriptionYesen_US
dc.description.abstractA 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO(g). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.en_US
dc.description.sponsorshipRoyal Society; Academy of Medical Sciences/the Wellcome Trust/the Government Department of Business, Energy and Industrial Strategy/the British Heart Foundation Springboard Awarden_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1021/acsomega.8b02154en_US
dc.rights(c) 2018 The Authors. This is an Open Access article distributed under the Creative Commons CC-BY license (https://creativecommons.org/licenses/by/4.0/)en_US
dc.subjectCarbon monoxide releaseen_US
dc.subjectCarbonylationen_US
dc.subjectElectron-deficient metal complexesen_US
dc.titleControlled Release of Carbon Monoxide from a Pseudo Electron- Deficient Organometallic Complexen_US
dc.status.refereedYesen_US
dc.typeArticleen_US
dc.type.versionPublished versionen_US
refterms.dateFOA2019-05-29T07:36:56Z


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