Controlled Release of Carbon Monoxide from a Pseudo Electron- Deficient Organometallic Complex
Publication date
2018-11-16Rights
(c) 2018 The Authors. This is an Open Access article distributed under the Creative Commons CC-BY license (https://creativecommons.org/licenses/by/4.0/)Peer-Reviewed
YesOpen Access status
openAccess
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A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO(g). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.Version
Published versionCitation
Pitto-Barry A and Barry NPE (2018) Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex. ACS Omega. 3(11): 15623-15627.Link to Version of Record
https://doi.org/10.1021/acsomega.8b02154Type
Articleae974a485f413a2113503eed53cd6c53
https://doi.org/10.1021/acsomega.8b02154