Polynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approach
| dc.contributor.author | Kobielska, Paulina A. | * |
| dc.contributor.author | Telford, Richard | * |
| dc.contributor.author | Rowlandson, J. | * |
| dc.contributor.author | Tian, M. | * |
| dc.contributor.author | Shahin, Z. | * |
| dc.contributor.author | Demessence, A. | * |
| dc.contributor.author | Ting, V.P. | * |
| dc.contributor.author | Nayak, Sanjit | * |
| dc.date.accessioned | 2018-08-08T11:54:01Z | |
| dc.date.available | 2018-08-08T11:54:01Z | |
| dc.date.issued | 2018-07 | |
| dc.identifier.citation | Kobielska PA, Telford R, Rowlandson J et al (2018) Polynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approach. ACS Applied Materials & Interfaces. 10(31): 25967-25971. | en_US |
| dc.identifier.uri | http://hdl.handle.net/10454/16535 | |
| dc.description | Yes | en_US |
| dc.description.abstract | A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g–1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K. | en_US |
| dc.description.sponsorship | EPSRC (EP/R01650X/1 for VPT, and EP/E040071/1 for MT) and the University of Bristol | en_US |
| dc.language.iso | en | en_US |
| dc.relation.isreferencedby | http://dx.doi.org/10.1021/acsami.8b10149 | en_US |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acsami.8b10149 | en_US |
| dc.subject | Complex-derived carbon | en_US |
| dc.subject | Coordination complex | en_US |
| dc.subject | Graphitic carbon | en_US |
| dc.subject | Hydrogen storage | en_US |
| dc.subject | Polynuclear complex | en_US |
| dc.subject | Porous carbon | en_US |
| dc.subject | Template precursor | en_US |
| dc.title | Polynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approach | en_US |
| dc.status.refereed | Yes | en_US |
| dc.date.Accepted | 2018-07-17 | |
| dc.date.application | 2018-07-17 | |
| dc.type | Article | en_US |
| dc.type.version | Accepted Manuscript | en_US |
| refterms.dateFOA | 2018-08-08T11:54:05Z |
