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dc.contributor.authorKobielska, Paulina A.*
dc.contributor.authorTelford, Richard*
dc.contributor.authorRowlandson, J.*
dc.contributor.authorTian, M.*
dc.contributor.authorShahin, Z.*
dc.contributor.authorDemessence, A.*
dc.contributor.authorTing, V.P.*
dc.contributor.authorNayak, Sanjit*
dc.date.accessioned2018-08-08T11:54:01Z
dc.date.available2018-08-08T11:54:01Z
dc.date.issued2018-07
dc.identifier.citationKobielska PA, Telford R, Rowlandson J et al (2018) Polynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approach. ACS Applied Materials & Interfaces. 10(31): 25967-25971.en_US
dc.identifier.urihttp://hdl.handle.net/10454/16535
dc.descriptionYesen_US
dc.description.abstractA highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g–1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.en_US
dc.description.sponsorshipEPSRC (EP/R01650X/1 for VPT, and EP/E040071/1 for MT) and the University of Bristolen_US
dc.language.isoenen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acsami.8b10149en_US
dc.subjectComplex-derived carbonen_US
dc.subjectCoordination complexen_US
dc.subjectGraphitic carbonen_US
dc.subjectHydrogen storageen_US
dc.subjectPolynuclear complexen_US
dc.subjectPorous carbonen_US
dc.subjectTemplate precursoren_US
dc.titlePolynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approachen_US
dc.status.refereedYesen_US
dc.date.Accepted2018-07-17
dc.date.application2018-07-17
dc.typeArticleen_US
dc.type.versionAccepted Manuscripten_US
dc.identifier.doihttps://doi.org/10.1021/acsami.8b10149
refterms.dateFOA2018-08-08T11:54:05Z


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