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dc.contributor.authorSaleem, Ayaan*
dc.contributor.authorKobielska, Paulina A.*
dc.contributor.authorHarms, K.*
dc.contributor.authorKatsikogianni, Maria G.*
dc.contributor.authorTelford, Richard*
dc.contributor.authorNovitchi, G.*
dc.contributor.authorNayak, Sanjit*
dc.date.accessioned2018-05-03T09:44:51Z
dc.date.available2018-05-03T09:44:51Z
dc.date.issued2018
dc.identifier.citationSaleem A, Kobielska PA, Harms K et al (2018) Transition metal complexes of a versatile polyalkoxy oxazolidine-based ligand derived from in situ cyclization. Dalton Transactions. 47: 6156-6165.en_US
dc.identifier.urihttp://hdl.handle.net/10454/15760
dc.descriptionYesen_US
dc.description.abstractOne-pot reaction between 8-hydroxyquinoline-2-carboxaldehyde (HQC) and tris(hydroxymethyl)aminomethane (TRIS) followed by in situ cyclization yielded an oxazolidine based ligand which produced four mononuclear complexes of MnII(1), CoII(2), NiII(3), ZnII(4), a tetranuclear iron (FeIII4) complex (5) and a trinuclear cobalt (CoIICoIII2) complex (6). Magnetic studies show dominant antiferromagnetic interaction in tetranuclear iron (FeIII4) complex 5 and presence of the slow relaxation of magnetisation in 6. The compounds were also studied for their antibacterial properties. The oxazolidine ligand (H3L2) of this study showed good antimicrobial activity not only against Gram-positive bacteria but against Gram-negative bacteria too. The antimicrobial efficacy of the metal complexes (1–6) is also reported.en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1039/C7DT04634Ken_US
dc.rights© 2018 Royal Society of Chemistry. Full-text reproduced in accordance with the publisher’s self-archiving policy.en_US
dc.subject8-hydroxyquinoline-2-carboxaldehyde; HQC; Tris(hydroxymethyl)aminomethane; TRIS; In situ cyclization; Liganden_US
dc.titleTransition metal complexes of a versatile polyalkoxy oxazolidine-based ligand derived from in situ cyclizationen_US
dc.status.refereedYesen_US
dc.date.Accepted2018-04-09
dc.date.application2018-04-10
dc.typeArticleen_US
dc.date.EndofEmbargo2019-04-11
dc.type.versionAccepted Manuscripten_US
dc.description.publicnotesThe full-text of this article will be released for public view at the end of the publisher's embargo period on 11 Apr 2019.en_US
refterms.dateFOA2018-07-29T01:36:28Z


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