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dc.contributor.authorSwift, Thomas*
dc.contributor.authorHoskins, Richard*
dc.contributor.authorTelford, Richard*
dc.contributor.authorPlenderleith, R.A.*
dc.contributor.authorPownall, David*
dc.contributor.authorRimmer, Stephen*
dc.date.accessioned2017-06-06T14:27:19Z
dc.date.available2017-06-06T14:27:19Z
dc.date.issued2017-07-28
dc.identifier.citationSwift T, Hoskins R, Telford R et al (2017) Analysis Using Size Exclusion Chromatography of poly(N-isopropyl acrylamide) using Methanol as an Eluent. Journal of Chromatography A. 1508: 16-23.en_US
dc.identifier.urihttp://hdl.handle.net/10454/12126
dc.descriptionYesen_US
dc.description.abstractSize Exclusion Chromatography is traditionally carried out in either aqueous or non-polar solvents. A system to present molar mass distributions of polymers using methanol as a mobile phase is presented. This is shown to be a suitable system for determining the molar mass distributions poly(N-isopropylacrylamide)s (PNIPAM); a polymer class that is often difficult to analyze by size exclusion chromatography. DOSY NMR was used to provide intrinsic viscosity data that was used in conjunction with a viscometric detector to provide absolute calibration. Then the utility of the system was shown by providing the absolute molar mass distributions of dispersed highly branched PNIPAM with biologically functional end groups.en_US
dc.description.sponsorshipWellcome Trusten_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttps://doi.org/10.1016/j.chroma.2017.05.050en_US
dc.rights© 2017 The Authors. This is an Open Access article distributed under the Creative Commons CC-BY license (http://creativecommons.org/licenses/by/4.0/)en_US
dc.subjectPNIPAM; Size Exclusion Chromatography; SEC; DOSY NMR; Methanol; Intrinsic Viscosityen_US
dc.titleAnalysis Using Size Exclusion Chromatography of poly(N-isopropyl acrylamide) using Methanol as an Eluenten_US
dc.status.refereedYesen_US
dc.date.Accepted2017-05-22
dc.date.application2017-05-25
dc.typeArticleen_US
dc.type.versionPublished versionen_US
refterms.dateFOA2018-07-25T13:35:13Z


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