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    Core (Polystyrene)−Shell [Poly(glycerol monomethacrylate)] Particles

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    Publication date
    2017
    Author
    Mckenzie, A.
    Hoskins, Richard
    Swift, Thomas
    Grant, Colin A.
    Rimmer, Stephen
    Keyword
    Core-shell; Particles; Emulsion polymerisation; Hydrogel; Protein adsorption
    Rights
    (c) 2017 ACS. This is an Open Access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html), which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
    Peer-Reviewed
    Yes
    
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    Abstract
    A set of water-swollen core−shell particles was synthesized by emulsion polymerization of a 1,3-dioxolane functional monomer in water. After removal of the 1,3- dioxolane group, the particles’ shells were shown to swell in aqueous media. Upon hydrolysis, the particles increased in size from around 70 to 100−130 nm. A bicinchoninic acid assay and ζ-potential measurements were used to investigate the adsorption of lysozyme, albumin, or fibrinogen. Each of the core−shell particles adsorbed significantly less protein than the noncoated core (polystyrene) particles. Differences were observed as both the amount of difunctional, cross-linking monomer and the amount of shell monomer in the feed were changed. The core−shell particles were shown to be resistant to protein adsorption, and the degree to which the three proteins adsorbed was dependent on the formulation of the shell.
    URI
    http://hdl.handle.net/10454/11485
    Version
    Published version
    Citation
    Mckenzie A, Hoskins R, Swift T et al (2017) Core (Polystyrene)−Shell [Poly(glycerol monomethacrylate)] Particles. ACS Applied Materials and Interfaces. 9(8): 7577-7590.
    Link to publisher’s version
    http://dx.doi.org/10.1021/acsami.6b15004
    Type
    Article
    Collections
    Life Sciences Publications

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