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dc.contributor.authorNalluri, S.K.M.*
dc.contributor.authorBerdugo, C.*
dc.contributor.authorJavid, Nadeem*
dc.contributor.authorFrederix, P.W.J.M.*
dc.contributor.authorUlijn, R.V.*
dc.date.accessioned2017-02-21T09:56:49Z
dc.date.available2017-02-21T09:56:49Z
dc.date.issued2014-05-30
dc.identifier.citationNalluri SKM, Berdugo C, Javid N et al (2014) Biocatalytic Self-Assembly of Supramolecular Charge Transfer Nanostructures Based on n-Type Semiconductor-Appended Peptide. Angewandte Chemie. International Ed. 53(23): 5882-5887.en_US
dc.identifier.urihttp://hdl.handle.net/10454/11425
dc.descriptionNoen_US
dc.description.abstractThe reversible in situ formation of a self-assembly building block (naphthalenediimide (NDI)–dipeptide conjugate) by enzymatic condensation of NDI-functionalized tyrosine (NDI-Y) and phenylalanine-amide (F-NH2) to form NDI-YF-NH2 is described. This coupled biocatalytic condensation/assembly approach is thermodynamically driven and gives rise to nanostructures with optimized supramolecular interactions as evidenced by substantial aggregation induced emission upon assembly. Furthermore, in the presence of di-hydroxy/alkoxy naphthalene donors, efficient charge-transfer complexes are produced. The dynamic formation of NDI-YF-NH2 and electronic and H-bonding interactions are analyzed and characterized by different methods. Microscopy (TEM and AFM) and rheology are used to characterize the formed nanostructures. Dynamic nanostructures, whose formation and function are driven by free-energy minimization, are inherently self-healing and provide opportunities for the development of aqueous adaptive nanotechnology.en_US
dc.language.isoenen_US
dc.relation.isreferencedbyhttp://dx.doi.org/10.1002/anie.201311158en_US
dc.subjectSelf-assembly; Charge transfer; Semi-conductor; Peptideen_US
dc.titleBiocatalytic Self-Assembly of Supramolecular Charge Transfer Nanostructures Based on n-Type Semiconductor-Appended Peptideen_US
dc.status.refereedYesen_US
dc.date.application2014-04-30
dc.typeArticleen_US
dc.type.versionNo full-text in the repositoryen_US


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