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    Nanoparticles of chitosan conjugated to organo-ruthenium complexes

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    Barry_Inorganic_Chemistry_Frontiers.pdf (2.241Mb)
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    Publication date
    2016
    Author
    Wang, Y.
    Pitto-Barry, Anaïs
    Habtemariam, A.
    Romero-Canelón, I.
    Sadler, P.J.
    Barry, Nicolas P.E.
    Keyword
    Nanoparticle conjugates; Organo-ruthenium complexes; Caffeic acid-modified chitosan; Ruthenium arene complexes; Drug delivery
    Rights
    © 2016 The Royal Society of Chemistry. Reproduced in accordance with the publisher's self-archiving policy. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
    Peer-Reviewed
    Yes
    
    Metadata
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    Abstract
    The synthesis of nanoparticles of conjugates of caffeic acid-modified chitosan with ruthenium arene complexes is described. The chemical structure and physical properties of the nanoparticles were characterised by electronic absorption spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), 1H NMR spectroscopy, dynamic light scattering (DLS), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and circular dichroism (CD) analysis. The multi-spectral results revealed that caffeic acid is covalently bound to chitosan and chelates to {Ru(p-cymene)Cl}+. The DLS studies indicated that the Ru–caffeic acid modified chitosan nanoparticles are well-defined and of nanometre size. Such well-defined nanocomposites of chitosan and metal complexes might find a range of applications, for example in drug delivery.
    URI
    http://hdl.handle.net/10454/11262
    Version
    Published version
    Citation
    Wang Y, Pitto-Barry A, Habtemariam A et al (2016) Nanoparticles of chitosan conjugated to organo-ruthenium complexes. Inorganic Chemistry Frontiers. 3(8): 1058-1064.
    Link to publisher’s version
    http://dx.doi.org/10.1039/C6QI00115G
    Type
    Article
    Collections
    Life Sciences Publications

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