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    Highly-branched poly(N-isopropyl acrylamide)s with core-shell morphology below the lower critical solution temperature

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    Publication date
    2014
    Author
    Plenderleith, R.A.
    Swift, Thomas
    Rimmer, Stephen
    Keyword
    Highly-branched poly(N-isopropyl acrylamide)s; Biphasic core–shell morphologies
    Rights
    © 2014 The Royal Society of Chemistry. Reproduced in accordance with the publisher's self-archiving policy.
    Peer-Reviewed
    Yes
    
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    Abstract
    Highly-branched poly(N-isopropyl acrylamide)s in water pass through coil-to-globule transitions. Using calorimetry and the colour change of a solvatochromic dye within the polymer, we show that some compositions have biphasic core–shell morphologies, with globular cores and open coil shells. The two-phase structure is favoured by increased branching and arises because the chain ends penetrate only to a limited degree into the polymer coil.
    URI
    http://hdl.handle.net/10454/11180
    Version
    Accepted Manuscript
    Citation
    Plenderleith R, Swift T and Rimmer S (2014) Highly-branched poly(N-isopropyl acrylamide)s with core-shell morphology below the lower critical solution temperature. RSC Advances. 4(92): 50932-50937.
    Link to publisher’s version
    http://dx.doi.org/10.1039/C4RA10076J
    Type
    Article
    Collections
    Life Sciences Publications

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