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A multinuclear 1H, 13C and 11B solid-state MAS NMR study of 16- and 18-electron organometallic ruthenium and osmium carborane complexes
Barry, Nicolas P.E. Kemp, T.F. Sadler, P.J. Hanna, J.V.
Barry, Nicolas P.E.
Kemp, T.F.
Sadler, P.J.
Hanna, J.V.
Publication Date
2014-02
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© 2014 The Royal Society of Chemistry. Reproduced in accordance with
the publisher's self-archiving policy. This article is licensed under a Creative Commons
Attribution 3.0 Unported Licence.
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2014-02-12
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Abstract
The first 1H, 13C, 31P and 11B solid state MAS NMR studies of electron-
deficient carborane-containing ruthenium and osmium
complexes [Ru/Os(p-cym)(1,2-dicarba-closo-dodecaborane-1,2-
dithiolate)] are reported. The MAS NMR data from these 16-electron
complexes are compared to those of free carborane-ligand
and an 18-electron triphenylphosphine ruthenium adduct, and
reveal clear spectral differences between 16- and 18-electron
organometallic carborane systems in the solid state.
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Citation
Barry NPE, Kemp TF, Sadler PJ et al (2014) A multinuclear 1H, 13C and 11B solid-state MAS
NMR study of 16- and 18-electron organometallic ruthenium and osmium carborane complexes.
Dalton Transactions. 43: 4945-4949.
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