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A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins
Li, R. Wen, Z.
Li, R.
Wen, Z.
Publication Date
2016-12
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(c) 2016 RSC. Full-text reproduced in accordance with the publisher's self-archiving policy.
Peer-Reviewed
Yes
Open Access status
openAccess
Accepted for publication
2016-11-10
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Abstract
A highly enantioselective rhodium catalysed asymmetric arylation
(RCAA) of nitroolefins with arylboronic acids is presented using
a newly developed, C1-symmetric, non-covalent interacted,
phellandrene derived, nordehydroabietyl amide-containing chiral
diene under mild conditions. Stereoelectronic effects were
studied, suggesting an activation of the bound substrate through
the secondary amide as a hydrogen-bond donor.
Version
Accepted manuscript
Citation
Li R, Wen Z and Wu N (2016) A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins. Organic and Biomolecular Chemistry. 14(47): 11080-11084.
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Article