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Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity
Naeem, Ayesha Ting, V.P. Hintermair, U. Tian, M. Telford, Richard Halim, Saaiba Nowell, H. Holynska, M. Teat, S.J. Scowen, Ian J.
Naeem, Ayesha
Ting, V.P.
Hintermair, U.
Tian, M.
Telford, Richard
Halim, Saaiba
Nowell, H.
Holynska, M.
Teat, S.J.
Scowen, Ian J.
Publication Date
2016
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© 2016 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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2016-05-17
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Abstract
Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.
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Naeem A, Ting VP, Hintermair U, Tian M, Telford R, Halim S, Nowell H, Holynska M, Teat SJ, Scowen IJ and Nayak S (2016) Mixed-linker approach in designing porous zirconium-based metal – organic frameworks with high hydrogen storage capacity. Chemical Communications. 52(50): 7826-7829.
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Article