Two Heterometallic Ionic Compounds with Isolated [3d] and [4f] Complex Units: Field-Induced Single-Ion Magnet (SIM) Behavior Observed from a Mononuclear Dysprosium(III) Complex
Novitchi, G. Holynska, M. Dehnen, S.
Novitchi, G.
Holynska, M.
Dehnen, S.
Publication Date
2014-07
End of Embargo
Supervisor
Rights
Peer-Reviewed
Yes
Open Access status
closedAccess
Accepted for publication
Institution
Department
Awarded
Embargo end date
Collections
Additional title
Abstract
Two new complexes, [Fe3(μ3-O)(inicH)6(H2O)3][Gd(NO3)6]·(NO3)4·nH2O (1) and [Fe3(μ3-O)(inicH)6(H2O)3][Dy(NO3)5 (H2O)]·(NO3)5·n(H2O) (2) with two isolated complex moieties, were generated when isonicotinic acid was treated with iron(III) nitrate and the corresponding lanthanide(III) nitrate in water. The structures were determined by single-crystal X-ray diffraction studies. In these compounds, the anionic lanthanide complexes are encapsulated by trinuclear [Fe3(μ3-O)(inicH)6(H2O)3]7+ cationic cluster units, which is facilitated by hydrogen-bonding interactions. Investigation of the magnetic properties reveals that 2 shows slow relaxation of magnetization at low magnetic field (Hdc = 1.0 kOe), with an energy barrier of 23 K originating from a single [Dy(NO3)5(H2O)]2– anion.
Version
No full-text in the repository
Citation
Nayak S, Novitchi G, Holynska M et al (2014) Two Heterometallic Ionic Compounds with Isolated [3d] and [4f] Complex Units: Field-Induced Single-Ion Magnet (SIM) Behavior Observed from a Mononuclear Dysprosium(III) Complex. European Journal of Inorganic Chemistry. 2014(19): 3065-3071.
Link to publisher’s version
Link to published version
Link to Version of Record
Type
Article
Qualification name
Notes
Errata: 2014(25): 4228 (http://onlinelibrary.wiley.com/enhanced/doi/10.1002/ejic.201402684)