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Ordered Aggregation of Benzamide Crystals Induced using a "Motif Capper" Additive.

Blagden, Nicholas
; 
Song, M.
; 
Davey, R.J.
; 
Seton, L.
; 
Seaton, Colin C.
Publication Date
2005
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Keywords
Organic compounds, Monoclinic lattices, Optical microscopy, Crystal growth from solutions, Aggregation, Solid-solid interface, Antifreeze proteins, Morphology
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Abstract
This paper reports on the growth of benzamide crystals in the presence of 2'-aminoacetophenone. The resulting self-replicating intergrowth of benzamide crystals gives rise to ordered crystal aggregates in which individuals share a common c*. This behavior is interpreted using the concept of a motif capper additive which is able to halt the extension of structural motifs at the surface of a growing crystal. In this case the additive was selected to terminate the hydrogen-bonding ribbons, which extend along the b axis of the benzamide structure.
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http://hdl.handle.net/10454/3554
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Citation
Blagden, N., Song, M., Davey, R.J. and Seton, L. et al. (2005). Ordered Aggregation of Benzamide Crystals Induced using a "Motif Capper" Additive. Crystal Growth & Design. Vol. 5, No. 2, pp. 467-471.
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https://doi.org/10.1021/cg0498204
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