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Easy and Fast Phase Transfer of CTAB Stabilised Gold Nanoparticles from Water to Organic Phase

Kittler, S.
Hickey, Stephen G.
Wolff, T.
Eychmüller, A.
Publication Date
28/02/2015
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21/11/2014
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Abstract
Spheric and anisotropic gold nanoparticles (GNPs) such as rods, stars or nanoprism prepared using hexadecyltrimethyl ammonium bromide (CTAB) as the stabilising agent have received a great deal of interest in the last years. The literature procedures exploited lead to GNPs in aqueous solution. We herein describe a fast, efficient, and cheap method to transfer particles of different shapes from water into toluene solution via ligand exchange (CTAB to dodecanethiol), which was mediated by acetone as a cosolvent. Absorption spectra and TEM-pictures before and after the transfer revealed that the particles survived the transfer intact and without change in shape.
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Kittler S, Hickey SG, Wolff T et al (2015) Easy and Fast Phase Transfer of CTAB Stabilised Gold Nanoparticles from Water to Organic Phase. Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics. 229(1-2): 235-245.
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