Metabolites of the Higher Fungi. Part 33. Grammicin, a novel bicyclic C7H6O4 furanoppyranol from the fungus Xylaria grammica (Mont) Fr.
Maitland, Derek J. Edwards, Raymond L. Pittayakhajonwut P. Whalley, A.J.S.
Maitland, Derek J.
Edwards, Raymond L.
Pittayakhajonwut P.
Whalley, A.J.S.
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2009-05-20
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Grammicin 1 from Xylaria grammica is identified as 4-hydroxy-4H-furo[2,3-b]pyran-2(7aH)-one by chemical and
physical methods. 4-Oxo-4H-pyran-3-acetic acid (¿-pyrone-3-acetic acid) 2 is a co-metabolite and the conversion of 1
into 2 is discussed.
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Edwards, R, Maitland, Derek J., Pittayakhajonwut, P., Whalley, Anthony.J.S. (2001). Metabolites of the Higher Fungi. Part 33. Grammicin, a novel bicyclic C7H6O4 furanoppyranol from the fungus Xylaria grammica (Mont) Fr. Journal of the Chemical Society Perkin Transactions 1. Vol.1, pp. 1296-1299.
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